Polyester polyol reactors

Polyol synthesis technology

H&S technology for generating aromatic polyester polyols (APP) from polyethylene terephthalate (PET) as well as phthalic acid anhydride (PA) is based on:

  • natural oil
  • adipic acid polyester

Process sequence and duration (polyol generating based on PET)

Process duration for generating PA based polyols makes approx. 12 hours.

Raw materials required for the processes

  • Polyethylene terephthalate (PET)
  • Phthalic acid anhydride (PA)
  • Adipic acid
  • Glycol
  • Monoethylene glycol
  • Glycerol
  • Catalysts
  • Natural oil

PET and PA polyols properties

PET based polyols are aromatic polyester polyol for application in rigid PU foam

Hydroxyl number: from 150 to 550 mg KOH/g (individually adaptable)
Acid number: <1,0 mg KOH/g
Aromatic content: 25-42%
Viscosity (25°C): 1.500-20.000 mPas
Appearance: viscous transparent liquid from colorless to light-brown color

PA based polyols are aromatic polyester polyol for application in rigid PU foam

Hydroxyl number: from 150 to 500 mg KOH/g (individually adaptable)
Acid number: 0-2,5 mg KOH/g
Aromatic content: 25-45%
Viscosity (25°C): 1.500–12.000 mPas
Appearance: viscous transparent liquid from colorless to light-brown color


Adipatic polyols

H&S also has developed a technology of generating adipates. Adipates are polyols based on adipic acid used for CASE applications (elastomers, shoe soles and coatings).

Product applications

Polyols based on PET and PA are high-quality polyester polyols, which fit perfectly into the formulations for insulation foams, cast resins, sealants or adhesives.


Application example

Spray foams

Reactor and peripheral equipment (Core unit)

 

H&S reactors for generating polyols based on PET and PA can be supplied with batch capacity from 1t to 40t.